Using distributed temperature sensing (DTS) technology in acid gas injection design     

Liaqat Ali  Russell E. Bentley  Alberto A. Gutierrez  Yosmar Gonzalez 《Acta Geotechnica》2014,9(1):135-144

The use of slickline distributed temperature sensing (SL-DTS) technology is becoming widespread due to its ease of operation and ability to acquire real-time multiple temperature traces inside the wellbore. Injection of treated acid gas (TAG)—a mixture of CO₂ and H₂S—into geologic formations has become an attractive technical and economic option for oil and gas producers and processors who are faced with regulations concerning excess sulfur and greenhouse gas emissions. Acid gas injection (AGI) into geologic formations is more economical and more flexible in dealing with varying TAG compositions than sulfur recovery units (SRUs) using the Claus process. SRUs do not achieve air quality standards and have high operation and maintenance costs. In addition, there is low demand for sulfur and sulfur disposal costs are high. The results of the analysis of SL-DTS data acquired in conjunction with step rate and pressure falloff (PFO) tests are presented in this paper. These tests were conducted to evaluate the injection potential of geologic formations. The injection zone consisted of a carbonate formation characterized by Karst features, vugs, and natural fractures. The SL-DTS data during the initial injection flow rate for the step rate test (SRT) indicated that high permeability zones accepted fluid at lower injection rates. An increasing number of discrete zones began to accept fluid as the injection rate was increased. The results of the SRT provided the fracture pressure of the formation. This information was used to design an AGI program that would avoid fracturing the formation while allowing for the required volume of TAG to be injected. The results of the PFO test provided information on the reservoir pressure and permeability and also indicated the presence of one or more hydraulic fractures. This case study of SL-DTS measurements made during a SRT and a PFO test for the design of an AGI well provides valuable insights into the potential of DTS technology and its use in AGI and carbon capture/sequestration (CCS) operations. Its findings could be applied to analyze injection potential of geological formations not only for AGI projects but also for CCS, and CO₂ enhanced oil recovery opportunities.  相似文献   

Technical, financial and location criteria for the design of land application system treatment     

Juana María Sanz  Ángel de Miguel  Irene de Bustamante  Alberto de Tomás  José Luis Goy 《Environmental Earth Sciences》2014,71(1):13-21

Conventional water treatments when downsized to cover the demands of small and scattered populations are costly and ineffective. In fact, many small towns cannot afford the high average treatment costs nor provide the skill and complex management requirements. Even when these facilities are available, waste water might not be properly treated. Land application system treatments (LAST) have been shown to be preferable on the basis of their technical effectiveness and financial viability. The recently approved Spanish regulations (RDL 1620/2007, pp 50369–50661) represent an opportunity for the implementation of well-designed LASTs. This paper presents an assessment methodology for the design of LASTs by combining technical, financial and location criteria. The method is applied to the design of LASTs to cover the water disposal demand of twelve municipalities located within the protected natural landscape, and surrounding areas of ‘El Rebollar’, Salamanca, Spain.  相似文献   

Human alteration of groundwater–surface water interactions (Sagittario River,Central Italy): implication for flow regime,contaminant fate and invertebrate response     

Mariachiara Caschetto  Maurizio Barbieri  Diana M. P. Galassi  Lucia Mastrorillo  Sergio Rusi  Fabio Stoch  Alessia Di Cioccio  Marco Petitta 《Environmental Earth Sciences》2014,71(4):1791-1807

Many rivers worldwide are undergoing severe man-induced alterations which are reflected also in changes of the degree of connectivity between surface waters and groundwater. Pollution, irrigation withdrawal, alteration of freshwater flows, road construction, surface water diversion, soil erosion in agriculture, deforestation and dam building have led to some irreversible species losses and severe changes in community composition of freshwater ecosystems. Taking into account the impact of damming and flow diversion on natural river discharge, the present study is aimed at (i) evaluating the effects of anthropogenic changes on groundwater/surface water interactions; (ii) analyzing the fate of nitrogenous pollutants at the floodplain scale; and (iii) describing the overall response of invertebrate assemblages to such changes. Hydrogeological, geochemical and isotopic data revealed short- and long-term changes in hydrology, allowing the assessment of the hydrogeological setting and the evaluation of potential contamination by nitrogen compounds. Water isotopes allowed distinguishing a shallow aquifer locally fed by zenithal recharge and river losses, and a deeper aquifer/aquitard system fed by surrounding carbonate aquifers. This system was found to retain ammonium and, through the shallow aquifer, release it in surface running waters via the hyporheic zone of the riverbed. All these factors influence river ecosystem health. As many environmental drivers entered in action offering a multiple-component artificial environment, a clear relationship between river flow alteration and benthic and hyporheic invertebrate diversity was not found, being species response driven by the combination of three main stressors: ammonium pollution, man-induced changes in river morphology and altered discharge regime.  相似文献   

FTIR spectroscopy of Ti-chondrodite,Ti-clinohumite,and olivine in deeply subducted serpentinites and implications for the deep water cycle   总被引：1，自引：0，他引：1  

Tingting Shen  Jőrg Hermann  Lifei Zhang  José Alberto Padrón-Navarta  Jing Chen 《Contributions to Mineralogy and Petrology》2014,167(4):1-15

Separated olivine grains from a deeply subducted serpentinized wehrlite (Changawuzi in the western Tianshan ultrahigh-pressure belt, China) were analysed with unpolarized transmission FTIR and the Ti contents were determined using LA-ICP-MS. The major bands in the olivine spectra display striking similarities to Ti-clinohumite and are interpreted as OH in lamellae. The quantification of the water content in lamellae requires calibration of the IR-absorption for such bands. We have obtained a new absorption coefficient for Ti-clinohumite of 0.125+/?0.017 ppm cm² based on polarized FTIR measurements on three orthogonal sections through a large single crystal of Ti-clinohumite from Val Malenco, which has a known water content of 1.53 wt%. The resulting water content in olivine using this calibration factor ranges from 440 to 2,600 ppm and correlates positively with the Ti content that ranges from 130 to 1,400 ppm. For the quantification of the water content in Ti-chondrodite and Ti-clinohumite that are associated with olivine, we developed a new method using attenuated total reflectance FTIR spectroscopy. Ti-chondrodite and Ti-clinohumite display similar IR bands at ~3,562, 3,525 and ~3,583–3,586 cm^?1. As in olivine, the water content and Ti content correlate in both Ti-clinohumite and Ti-chondrodite, indicating an intergrowth of these minerals, which has been confirmed by TEM analyses. Our results confirm previous suggestions that there is a strong correlation between the Ti content of ultramafic rocks and their capacity to transport water to the deeper mantle in subduction zones beyond conditions where hydrous phases are stable.  相似文献   

Age and origin of the lowlands of Mars     

Alberto G Fairén  James M Dohm 《Icarus》2004,168(2):277-284

One of the many significant findings of the Mars Global Surveyor mission is the presence of hundreds of quasi-circular depressions (QCDs) observed from high-resolution MOLA topography data. Their presence has recently been interpreted to reflect a northern lowlands that archive some of the earliest recorded rocks on Mars, mostly below a veneer of Hesperian and Amazonian materials. Here we analyze these data, coupled with a recent synthesis of geologic, geophysical, geomorphic, topographic, and magnetic information. Such analysis allows us to suggest a potential plate tectonic phase during the recorded Early into Middle Noachian martian history that transitioned into a monoplate world with episodic magmatic-driven activity persisting to present. This working hypothesis is based on: (1) the observation that the basement of the northern plains is younger than the basement of the southern highlands, but older than the material exposures of the cratered highlands, suggesting different formational ages for each one of the three geologic-time units; (2) the observation that parts of the very ancient highland's crust are highly magnetized, thus suggesting that most if not all of the formation of the lowlands basement postdates the shut off of the martian dynamo, some 4 Gyr ago, and so allowing hundreds of millions of years for the shaping of the buried lowlands. Consequently, the role of endogenic processes in the earliest geological evolution of Mars (Early perhaps into Middle Noachian) requires reconsideration, since MOLA topographic and MGS magnetic data afford a temporal window sufficient for very early, non-primordial shaping of the northern lowlands' basement.  相似文献   

The marine Jurassic of Argentina： a biostratigraphic framework     

Alberto C. Riccardi 《《幕》》2008,31(3):326-335

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Microbial signatures in sabkha evaporite deposits of Chott el Gharsa (Tunisia) and their astrobiological implications   总被引：1，自引：0，他引：1  

Roberto Barbieri  Nunzia Stivaletta 《Planetary and Space Science》2006,54(8):726-736

This study investigates the geomicrobiological potential of Upper Pleistocene evaporite deposits of the Chott el Gharsa, a wide continental sabkha in southern Tunisia. Organic and inorganic-derived biosignatures are mostly contained in microcrystalline, laminated gypsum lithofacies consisting of light/dark alternations of concordant laminae, which have precipitated from high salt concentrated waters. These biosignatures include mineralized microbial-interpreted morphologies, such as mucilage, rods, and microfibers, and dumbbell morphologies in the hollow cores of dolomite crystals that are associated with sulfates. Mineral products that are induced by microbial activity and their organic compounds lead to the formation of lenticular-shaped gypsum crystals, with a high length/width ratio, dolomite precipitation and formation of pyrite framboids. Morphological and structural aspects of these biosignatures, and their composition, in laminated, dolomite-rich sulfate deposits could be detected through microscopic investigations and micro-analyses performed by the instrumentation that is planned for ongoing Mars sample return missions.  相似文献   

Putative Meteoritic Craters in Río Cuarto (Central Argentina) Interpreted as Eolian Structures     

Cione  Alberto L.  Tonni  Eduardo P.  San Cristóbal  Jorge  Hernández  Pedro J.  Benítez  Adrián  Bordignon  Fernando  Perí  Jorge A. 《Earth, Moon, and Planets》2002,91(1):9-24

Ten oblong aligned depressions in the Río Cuarto area (provincia de Córdoba, Argentina) were supposed to be the result of very-low-angle Holocene meteoroid impacts. However, we consider that authors that studied the structures did not demonstrated their extraterrestrial origin. We suggest that an eolian origin for the structures of Río Cuarto is more likely. Actually, these landforms integrate large systems of similar deflation/accumulation geoforms aligned according to predominant winds during different periods.  相似文献   

The helicity constraint in turbulent dynamos with shear     

Axel Brandenburg  Alberto Bigazzi  Kandaswamy Subramanian 《Monthly notices of the Royal Astronomical Society》2001,325(2):685-692

The evolution of magnetic fields is studied using simulations of forced helical turbulence with strong imposed shear. After some initial exponential growth, the magnetic field develops a large-scale travelling wave pattern. The resulting field structure possesses magnetic helicity, which is conserved in a periodic box by the ideal magnetohydrodynamics equations and can hence only change on a resistive time-scale. This strongly constrains the growth time of the large-scale magnetic field, but less strongly constrains the length of the cycle period. Comparing this with the case without shear, the time-scale for large-scale field amplification is shortened by a factor Q , which depends on the relative importance of shear and helical turbulence, and which also controls the ratio of toroidal to poloidal field. The results of the simulations can be reproduced qualitatively and quantitatively with a mean-field α Ω-dynamo model with alpha-effect and turbulent magnetic diffusivity coefficients that are less strongly quenched than in the corresponding α ²-dynamo.  相似文献   

The NASA Astrophysics Data System: Free Access to the Astronomical Literature On-line and through Email     

Guenther Eichhorn  Alberto Accomazzi  Carolyn S. Grant  Michael J. Kurtz  Stephen S. Murray 《Astrophysics and Space Science》2002,282(1):299-340

The Astrophysics Data System (ADS) provides access to the astronomical literature through the World Wide Web. It is a NASA funded project and access to all the ADS services is free to everybody world-wide. The ADS Abstract Service allows the searching of four databases with abstracts in Astronomy, Instrumentation, Physics/Geophysics, and the LANL Preprints with a total of over 2.2 million references. The system also provides access to reference and citation information, links to on-line data, electronic journal articles, and other on-line information. The ADS Article Service contains the full articles for most of the astronomical literature back to volume 1. It contains the scanned pages of all the major journals (Astrophysical Journal, Astronomical Journal, Astronomy & Astrophysics, Monthly Notices of the Royal Astronomical Society, and Solar Physics), as well as most smaller journals back to volume 1.The ADS can be accessed through any web browser without signup or login. Alternatively an email interface is available that allows our users to execute queries via email and to retrieve scanned articles via email. This might be interesting for users on slow or unreliable links, since the email system will retry sending information automatically until the transfer is complete. There are now 9 mirror sites of the ADS available in different parts of the world to improve access. The ADS is available at: http://ads.harvard.edu This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献